Simple, Axial Ligand-Mediated Route to Water-Soluble Iridium Corroles
نویسندگان
چکیده
منابع مشابه
A water-soluble iridium(III) porphyrin.
This work reports the synthesis and characterization of the first water-soluble iridium porphyrin, iridium(iii) diaqua porphyrin [Ir(III)(TSPP)(OH(2))(2)](3-) (1, TSPP = tetra-p-sulfonatophenyl porphyrin). The structure of 1 was unequivocally determined by single crystal X-ray analysis. Benzo-18-crown-6-ether is essential for producing single crystals suitable for X-ray analysis.
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متن کاملNear-IR phosphorescence of iridium(III) corroles at ambient temperature.
The photophysical properties of Ir(III) corroles differ from those of phosphorescent porphyrin complexes, cyclometalated and polyimine Ir(III) compounds, and other luminescent metallocorroles. Ir(III) corrole phosphorescence is observed at ambient temperature at wavelengths much longer (>800 nm) than those of most Ir(III) phosphors. The solvatochromic behavior of Ir(III)-corrole Soret and Q abs...
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ژورنال
عنوان ژورنال: ACS Omega
سال: 2021
ISSN: 2470-1343,2470-1343
DOI: 10.1021/acsomega.1c02399